It looks like you are using legacy bios. mine is using uefi with a zfs rpool

proxmox-boot-tool status
Re-executing '/usr/sbin/proxmox-boot-tool' in new private mount namespace..
System currently booted with uefi
31FA-87E2 is configured with: uefi (versions: 6.5.11-8-pve, 6.5.13-5-pve)

However, like with everything a method always exists to get it done. Or not if you are concerned.

If you are interested it would look like…

Pool Upgrade

sudo zpool upgrade 

Confirm Upgrade

sudo zpool status

Refresh boot config

sudo pveboot-tool refresh

Confirm Boot configuration

cat /boot/grub/grub.cfg

You are looking for directives like this to see if they are indeed pointing at your existing rpool

root=ZFS=rpool/ROOT/pve-1 boot=zfs quiet

here is my file if it helps you compare…

#
# DO NOT EDIT THIS FILE
#
# It is automatically generated by grub-mkconfig using templates
# from /etc/grub.d and settings from /etc/default/grub
#

### BEGIN /etc/grub.d/000_proxmox_boot_header ###
#
# This system is booted via proxmox-boot-tool! The grub-config used when
# booting from the disks configured with proxmox-boot-tool resides on the vfat
# partitions with UUIDs listed in /etc/kernel/proxmox-boot-uuids.
# /boot/grub/grub.cfg is NOT read when booting from those disk!
### END /etc/grub.d/000_proxmox_boot_header ###

### BEGIN /etc/grub.d/00_header ###
if [ -s $prefix/grubenv ]; then
  set have_grubenv=true
  load_env
fi
if [ "${next_entry}" ] ; then
   set default="${next_entry}"
   set next_entry=
   save_env next_entry
   set boot_once=true
else
   set default="0"
fi

if [ x"${feature_menuentry_id}" = xy ]; then
  menuentry_id_option="--id"
else
  menuentry_id_option=""
fi

export menuentry_id_option

if [ "${prev_saved_entry}" ]; then
  set saved_entry="${prev_saved_entry}"
  save_env saved_entry
  set prev_saved_entry=
  save_env prev_saved_entry
  set boot_once=true
fi

function savedefault {
  if [ -z "${boot_once}" ]; then
    saved_entry="${chosen}"
    save_env saved_entry
  fi
}
function load_video {
  if [ x$feature_all_video_module = xy ]; then
    insmod all_video
  else
    insmod efi_gop
    insmod efi_uga
    insmod ieee1275_fb
    insmod vbe
    insmod vga
    insmod video_bochs
    insmod video_cirrus
  fi
}

if loadfont unicode ; then
  set gfxmode=auto
  load_video
  insmod gfxterm
  set locale_dir=$prefix/locale
  set lang=en_US
  insmod gettext
fi
terminal_output gfxterm
if [ "${recordfail}" = 1 ] ; then
  set timeout=30
else
  if [ x$feature_timeout_style = xy ] ; then
    set timeout_style=menu
    set timeout=5
  # Fallback normal timeout code in case the timeout_style feature is
  # unavailable.
  else
    set timeout=5
  fi
fi
### END /etc/grub.d/00_header ###

### BEGIN /etc/grub.d/05_debian_theme ###
set menu_color_normal=cyan/blue
set menu_color_highlight=white/blue
### END /etc/grub.d/05_debian_theme ###

### BEGIN /etc/grub.d/10_linux ###
function gfxmode {
        set gfxpayload="${1}"
}
set linux_gfx_mode=
export linux_gfx_mode
menuentry 'Proxmox VE GNU/Linux' --class proxmox --class gnu-linux --class gnu --class os $menuentry_id_option 'gnulinux-simple-/dev/sdc3' {
        load_video
        insmod gzio
        if [ x$grub_platform = xxen ]; then insmod xzio; insmod lzopio; fi
        insmod part_gpt
        echo    'Loading Linux 6.5.13-5-pve ...'
        linux   /ROOT/pve-1@/boot/vmlinuz-6.5.13-5-pve root=ZFS=/ROOT/pve-1 ro       root=ZFS=rpool/ROOT/pve-1 boot=zfs quiet
        echo    'Loading initial ramdisk ...'
        initrd  /ROOT/pve-1@/boot/initrd.img-6.5.13-5-pve
}
submenu 'Advanced options for Proxmox VE GNU/Linux' $menuentry_id_option 'gnulinux-advanced-/dev/sdc3' {
        menuentry 'Proxmox VE GNU/Linux, with Linux 6.5.13-5-pve' --class proxmox --class gnu-linux --class gnu --class os $menuentry_id_option 'gnulinux-6.5.13-5-pve-advanced-/dev/sdc3' {
                load_video
                insmod gzio
                if [ x$grub_platform = xxen ]; then insmod xzio; insmod lzopio; fi
                insmod part_gpt
                echo    'Loading Linux 6.5.13-5-pve ...'
                linux   /ROOT/pve-1@/boot/vmlinuz-6.5.13-5-pve root=ZFS=/ROOT/pve-1 ro       root=ZFS=rpool/ROOT/pve-1 boot=zfs quiet
                echo    'Loading initial ramdisk ...'
                initrd  /ROOT/pve-1@/boot/initrd.img-6.5.13-5-pve
        }
        menuentry 'Proxmox VE GNU/Linux, with Linux 6.5.13-5-pve (recovery mode)' --class proxmox --class gnu-linux --class gnu --class os $menuentry_id_option 'gnulinux-6.5.13-5-pve-recovery-/dev/sdc3' {
                load_video
                insmod gzio
                if [ x$grub_platform = xxen ]; then insmod xzio; insmod lzopio; fi
                insmod part_gpt
                echo    'Loading Linux 6.5.13-5-pve ...'
                linux   /ROOT/pve-1@/boot/vmlinuz-6.5.13-5-pve root=ZFS=/ROOT/pve-1 ro single       root=ZFS=rpool/ROOT/pve-1 boot=zfs
                echo    'Loading initial ramdisk ...'
                initrd  /ROOT/pve-1@/boot/initrd.img-6.5.13-5-pve
        }
        menuentry 'Proxmox VE GNU/Linux, with Linux 6.5.11-8-pve' --class proxmox --class gnu-linux --class gnu --class os $menuentry_id_option 'gnulinux-6.5.11-8-pve-advanced-/dev/sdc3' {
                load_video
                insmod gzio
                if [ x$grub_platform = xxen ]; then insmod xzio; insmod lzopio; fi
                insmod part_gpt
                echo    'Loading Linux 6.5.11-8-pve ...'
                linux   /ROOT/pve-1@/boot/vmlinuz-6.5.11-8-pve root=ZFS=/ROOT/pve-1 ro       root=ZFS=rpool/ROOT/pve-1 boot=zfs quiet
                echo    'Loading initial ramdisk ...'
                initrd  /ROOT/pve-1@/boot/initrd.img-6.5.11-8-pve
        }
        menuentry 'Proxmox VE GNU/Linux, with Linux 6.5.11-8-pve (recovery mode)' --class proxmox --class gnu-linux --class gnu --class os $menuentry_id_option 'gnulinux-6.5.11-8-pve-recovery-/dev/sdc3' {
                load_video
                insmod gzio
                if [ x$grub_platform = xxen ]; then insmod xzio; insmod lzopio; fi
                insmod part_gpt
                echo    'Loading Linux 6.5.11-8-pve ...'
                linux   /ROOT/pve-1@/boot/vmlinuz-6.5.11-8-pve root=ZFS=/ROOT/pve-1 ro single       root=ZFS=rpool/ROOT/pve-1 boot=zfs
                echo    'Loading initial ramdisk ...'
                initrd  /ROOT/pve-1@/boot/initrd.img-6.5.11-8-pve
        }
}

### END /etc/grub.d/10_linux ###

### BEGIN /etc/grub.d/20_linux_xen ###

### END /etc/grub.d/20_linux_xen ###

### BEGIN /etc/grub.d/20_memtest86+ ###
### END /etc/grub.d/20_memtest86+ ###

### BEGIN /etc/grub.d/30_os-prober ###
### END /etc/grub.d/30_os-prober ###

### BEGIN /etc/grub.d/30_uefi-firmware ###
menuentry 'UEFI Firmware Settings' $menuentry_id_option 'uefi-firmware' {
        fwsetup
}
### END /etc/grub.d/30_uefi-firmware ###

### BEGIN /etc/grub.d/40_custom ###
# This file provides an easy way to add custom menu entries.  Simply type the
# menu entries you want to add after this comment.  Be careful not to change
# the 'exec tail' line above.
### END /etc/grub.d/40_custom ###

### BEGIN /etc/grub.d/41_custom ###
if [ -f  ${config_directory}/custom.cfg ]; then
  source ${config_directory}/custom.cfg
elif [ -z "${config_directory}" -a -f  $prefix/custom.cfg ]; then
  source $prefix/custom.cfg
fi
### END /etc/grub.d/41_custom ###

You can see the lines by the linux sections.